Abstract
The decomposition of hydrazine vapors on the surface of single-crystalline germanium at 650oC is studied. This catalytic reaction proceeds according to the scheme 3N2H4→4NH3+N2. Ammonia corresponds to an equimolar amount of chemisorbed hydrazine (nN2H4(g)→nNH3(g)+(NH)n(ads) )..
References
L.F.Audigieth, P.H.Mohr.Chem. Eng. News, 1948, 26, 3746.
L.F.Audrieth, B.A.Ogg.The Chemistry of Hydrazine.Wiley,1951, 244.
E.W.Schmidt.One hundred years of hydrazine chemistry.Third Conference on Environmental Chemistry of Hydrazine Fuels. 1987, (1-16).
A.Krishnadasan, A.Kennedy et al. Amer. Industrial Medic., 2007, 50, 383.
Rocketandspacecraftpropulsion. Ed.: J.L.Turner, 2009, Prax. Publ. LTD,104.
E.W.Schmidt, M.S.Gordon. Zeitsch. Phys. Chem., 2013, 227, 9.
Y.Chen, Ch.Zhaoet al. Analyst. 2023, 4,856.
K.Yan, L.Yan et al. Environm. Res., 2023, 238, 117081.
Y.Zhang, G. Zhu et al.Sustainable Energy & Fuels, 2023, 7, 2594.
F.Luo, S.Pan et al. Adv. Sci., 2023, 10, 2305058.
V.A.Burilov, R.N.Belov et al.Chem. Bull., 2023, 72, 948.
T.Rennebaum, D. van Gerven et al. Chemistry, 2024, 30, e202302526.
V.A.Matyshak, O.N.Silchenkova. Kinet.Catal. 2022,l 63, 339.
D.Motta, I.Barlocco et al. Nanomaterials, 2021, 11, 1340.
Y.Cheng, X.Wu, H.Xu. Sustainable Energy Fuels, 2019,3, 343.
S.Pakdehi, F.Shirvani, R.Zolfaghari. Arch. Thermod., 2019, 40, 151.
X.Lu, F.Samantha et al. PhysChemChemPhys, 2020, 22, 3883.
V.M.Frolov. Kinet. Catal., 1965, 6, 149.
K.Mallem,S.V.Jagadeesh Chandra et al.Nanosci. Nanotechn., 2020, 20,1039.
Y.Ma, M.Wang, X.Zhou. Energy Chem., 2020, 44, 24.
Z.Huang, R.Su et al. Ceram. Intern., 2018, 4, 10858.
Sh.Kim,G.Hwanget al. Advanced Functional Mater., 2017, 7, 1605975.
G.Maggoini, S.Carturan et al. Appl. Surface Sci., 2017, 393, 119.
Y.O.Yayak,Y.Sozenet al. Appl. Surface Sci., 2022, 572, 15136.
I.Nakhutsrishvili. Oriental J. Chem., 2020, 36, 850.
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Copyright (c) 2024 Georgian Scientists