Abstract
The high-temperature oxidation of FeCr(La) and Cr(Ce) alloys was studied by thermogravimetry. The kinetic dependence of the FeCr(La) mass change has a specific form due to the simultaneous occurrence of scale evaporation and reduction of the reaction surface. The latter is due to the formation of diffusion barriers from lanthanum chromite. The kinetic dependence of the mass change of Cr(Ce) has an identical form. Based on this identity, it was suggested that diffusion barriers can also exist in the Cr(Ce) alloy, as is the case for the FeCr(La) alloy.
References
Y.Liang, L.V.Haotian, W.Chunlei, G.Qianming, C.Hao, Z.Chi, Y. Zhigang Mechanism of reactive element effect – oxide pegging Acta Metallurg. Sin., (34) 2021, pp. 182-190
N.K.Othman, A.Jalar, N.Othman, D.J.Young Effect of lanthanum on Fe-25Cr alloys under cyclic oxidation Adv. Mater. Res., (97/101) 2010, pp.1212-1215
O.Mikadze,I.Nakhutsrishvili,N.Maisuradze,G.Mikadze Kinetic regularities of growth of scale on heat resisting alloys with barrier layers of stable qxides Metallofiz. Noveish. Tekhnolog. (Metallophysics and Advanced Technologies), (29)2007, pp. 1507-1513.
M.F.Pillis, O.V.Correa, L.V. Ramanathan High-temperature corrosion behavior of yttrium dioxide coated Fe-20Cr alloy Materials Res., (19)2016, pp. 611-617
D.A.Downham, R.J.Hussey, D.F.Mitchell, M.J.Graham Segregation of cerium in chromia scales Prooc. Int. Symp. on high-temperature oxidation and sulphidation processes Hamilton, Ontario, Canada, 1990, aug.26-30, pp.101-106
I.Nakhutsrishvili Some formal aspects of Tedmon's kinetics: Growth and sublimation of Ge3N4 Technical Sci. and Technologies, (5)2016, pp.19-22
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.